I found PS a bit confusing at first because I started with vector first, mostly Freehand, then Illy. So, I started trying to do just one thing at a time, so it wouldn't be so overwhelming. It's a lot like playing the guitar, it's easy to do a few simple things, hard as hell to master. There was no web to search out when I started, so I had to learn a lot through reading and trying out what I read. Just take it slow, you'll be fine.