James, you can't mix RGB inks. Yes, RGB is additive, it's also about light, not ink. When you combine RGB full values, the result is white light. Red, Green and Blue are the primary colors of white light. If you mix Red, Green and Blue inks, you will get a bucket of mud. CMYK is the subtractive process, because, White light with the Red subtracted out leave the Green and Blue, which is called Cyan. White light with the Green subtracted out leaves the Red and Blue, which is Magenta, and White light with the Blue subtracted out leaves Red and Green, which becomes the Yellow, which sounds weird I know, but accept it as fact. Now, in theory, if you put 100% Cyan, 100% Yellow, and 100% Magenta on top of each other, you will get Black. But that doesn't happen, mainly because the Cyan, Magenta and Yellow inks are not 100% pure, causing the breakdown in theory/practice. Thus, Black (K) was added to the mix, and only prints in the deepest of shadows.
Steve